My recommendations from personal experience:
25gr 3F max for steel frame, 18 for brassers.
For most accurate loads, 18-20 on a steel Navy, 15-18 on a brasser.
Check your cylinder bore diameters before deciding on a .375 RB. I've had several brass Navies with .375 nominal bore that needed a .380 RB rather than .375.
Caps; Remington #10...IF you can find them. The fit stock nipples tightly without squeezing and don't tend to frag as much as other brands. RWS 1075s work well too, but also hard to come by. If you find a source for either, spend the extra $$$ and stock up. Who knows if and when Remington will resume producing components again?